Electrochemical phase formation: classical and atomistic theoretical models

被引：18

作者：

Milchev, Alexander ^{[1
]}

机构：

[1] Bulgarian Acad Sci, Evgeni Budevski Inst Electrochem & Energy Syst, Acad G Bonchev Str Bl 10, BU-1113 Sofia, Bulgaria

来源：

NANOSCALE | 2016年 / 8卷 / 29期

关键词：

ELECTROLYTIC NUCLEATION; ACTIVE-SITES; SURFACES; GROWTH; REALITY; SILVER; VAPOR;

D O I：

10.1039/c6nr02354a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The process of electrochemical phase formation at constant thermodynamic supersaturation is considered in terms of classical and atomistic nucleation theories. General theoretical expressions are derived for important thermodynamic and kinetic quantities commenting also upon the correlation between the existing theoretical models and experimental results. Progressive and instantaneous nucleation and growth of multiple clusters of the new phase are briefly considered, too.

引用

页码：13867 / 13872

页数：6

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