An overview of some recent advances in DOPO-derivatives: Chemistry and flame retardant applications

被引：321
作者：
Salmeia, Khalifah A. [1 ]
Gaan, Sabyasachi [1 ]
机构：
[1] EMPA Swiss Fed Labs Mat Sci & Technol, Addit & Chem Grp, Gallen, Switzerland
来源：
POLYMER DEGRADATION AND STABILITY | 2015年 / 113卷
关键词：
9,10-Dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO); Phosphorus-containing compounds; Reaction mechanism; DOPO-derivatives; Flame retardants; ATHERTON-TODD REACTION; EPOXY-RESINS; 9,10-DIHYDRO-9-OXA-10-PHOSPHAPHENANTHRENE-10-OXIDE DOPO; THERMAL-PROPERTIES; HYBRID MATERIALS; T-G; PHOSPHORUS; ACID; PERFORMANCE; STABILITY;
D O I：
10.1016/j.polymdegradstab.2014.12.014
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Owing to the toxicity and environmental concerns of halogen-containing flame retardants, phosphorus-containing flame retardants have attracted much attention as ecofriendly substitutes. Synthesis of organophosphorus compounds based on 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and its application as flame retardant have created much attention in the flame retardant community. Various chemical reactions and synthetic approaches are followed to develop numerous derivatives of DOPO. This review focuses on the recent advances in DOPO chemistry, classifying its derivatives based on the chemical reactions and functional groups. The reaction mechanisms of each specific reaction for DOPO derivatization are discussed in detail. Additionally some characteristic applications of these DOPO-derivatives with important flammability performance are also reported in this short review. (C) 2014 Elsevier Ltd. All rights reserved.
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页码：119 / 134
页数：16
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