New experimental results for the vapor-liquid equilibrium of the binary system (trioxane plus water) and the ternary system (formaldehyde plus trioxane plus water)

被引：31

作者：

Albert, M ^{[1
]}

Hasse, H ^{[1
]}

Kuhnert, C ^{[1
]}

Maurer, G ^{[1
]}

机构：

[1] Univ Kaiserslautern, Lehrstuhl Tech Thermodynam, D-67653 Kaiserslautern, Germany

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2005年 / 50卷 / 04期

关键词：

D O I：

10.1021/je050015i

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

New experimental results for the vapor-liquid equilibrium of the binary system (trioxane + water) at 393 K and 413 K and the ternary system (formaldehyde + trioxane + water) at 413 K and around 450 kPa are reported and compared with predictions/correlations using a physicochemical model combining the UNIFAC equation for the Gibbs excess energy with chemical reaction equilibria. Revised parameters of the model for these systems are reported.

引用

页码：1218 / 1223

页数：6

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