New experimental results for the vapor-liquid equilibrium of the binary system (trioxane plus water) and the ternary system (formaldehyde plus trioxane plus water)

被引：30
作者：
Albert, M [1 ]
Hasse, H [1 ]
Kuhnert, C [1 ]
Maurer, G [1 ]
机构：
[1] Univ Kaiserslautern, Lehrstuhl Tech Thermodynam, D-67653 Kaiserslautern, Germany
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2005年 / 50卷 / 04期
关键词：
D O I：
10.1021/je050015i
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
New experimental results for the vapor-liquid equilibrium of the binary system (trioxane + water) at 393 K and 413 K and the ternary system (formaldehyde + trioxane + water) at 413 K and around 450 kPa are reported and compared with predictions/correlations using a physicochemical model combining the UNIFAC equation for the Gibbs excess energy with chemical reaction equilibria. Revised parameters of the model for these systems are reported.
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页码：1218 / 1223
页数：6
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