Mn(IV) and Co(III)-complexes of -OH-rich ligands possessing O2N, O3N and O4N cores:: syntheses, characterization and crystal structures

被引：37

作者：

Dey, M

Rao, CP ^{[1
]}

Saarenketo, PK

Rissanen, K

Kolehmainen, E

Guionneau, P

机构：

[1] Indian Inst Technol, Dept Chem, Bioinorgan Lab, Bombay 400076, Maharashtra, India

[2] Univ Jyvaskyla, Dept Chem, FIN-40351 Jyvaskyla, Finland

[3] CNRS, UPR 9048, Inst Chim Mat Condensee Bordeaux, F-33608 Pessac, France

来源：

POLYHEDRON | 2003年 / 22卷 / 27期

关键词：

manganese(IV) complex; cobalt(III) complex; crystal structure; magnetic moment; hydrogen bonds;

D O I：

10.1016/j.poly.2003.09.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mn(IV) and Co(III) complexes of tridentate -OH-rich ligands possessing O2N, O3N and O4N donor sets were synthesized, characterized and their structures were established by single crystal X-ray diffraction, where the binding core is O4N2. In the structurally characterized complexes, the coordination geometry about the metal ion was found to be distorted octahedral. (C) 2003 Elsevier Ltd. All rights reserved.

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页码：3515 / 3521

页数：7

相关论文

共 34 条

[1]

ALGOOD GS, 1986, J BACTERIOL, V168, P563

[2] COMPLETION AND REFINEMENT OF CRYSTAL-STRUCTURES WITH SIR92 [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, C ;

GUAGLIARDI, A .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1993, 26 (pt 3) :343-350

[3] Structures of four types of novel high-valent manganese complexes obtained by the reactions of KMnO4 with tridentate Schiff base ligands [J].

Asada, H ;

Ozeki, M ;

Fujiwara, M ;

Matsushita, T .

POLYHEDRON, 2002, 21 (12-13) :1139-1148

[4] MONONUCLEAR CIS-DIOXOVANADIUM(V) ANIONIC COMPLEXES [VO(2)L](-)(H(2)L=[1+1] SCHIFF-BASE DERIVED FROM SALICYLALDEHYDE (OR SUBSTITUTED DERIVATIVES) AND 2-AMINO-2-METHYLPROPAN-1-OL) - SYNTHESIS, STRUCTURE, SPECTROSCOPY, ELECTROCHEMISTRY AND REACTIVITY STUDIES [J].

ASGEDOM, G ;

SREEDHARA, A ;

KIVIKOSKI, J ;

VALKONEN, J ;

RAO, CP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (14) :2459-2466

[5] Alkoxo bound monooxo- and dioxovanadium(V) complexes: Synthesis, characterization, x-ray crystal structures, and solution reactivity studies [J].

Asgedom, G ;

Sreedhara, A ;

Kivikoski, J ;

Valkonen, J ;

Kolehmainen, E ;

Rao, CP .

INORGANIC CHEMISTRY, 1996, 35 (19) :5674-5683

[6] Studies of the binding modes of carboxylate donors with manganese(III) complexes containing tetradentate Schiff base ligands.: Crystal structures of the complexes [Mn(3-CH3Osalpn)(HO2CC6H4CO2)]n and [{Mn(5-NO2salpn)(OH)(H2O)} {Mn(5-NO2salpn)-(HO2CC6H4CO2)(H2O)}]•C2H5OH [J].

Bermejo, MR ;

Fondo, M ;

García-Deibe, A ;

González, AM ;

Sousa, A ;

Sanmartín, J ;

McAuliffe, CA ;

Pritchard, RG ;

Watkinson, M ;

Lukov, V .

INORGANICA CHIMICA ACTA, 1999, 293 (02) :210-217

[7] COMPLEXES OF THE LIGAND 1,5,8,12-TETRAAZADODECANE (3,2,3-TET) WITH MANGANESE(III) AND WITH A VALENCE-TRAPPED MANGANESE(III) MANGANESE(IV) HEXANUCLEAR ARRAY - CRYSTAL AND MOLECULAR-STRUCTURES OF [TRANS-MN(3-IOBZ)2(3,2,3-TET)](CLO4) AND [MN6(3,2,3-TET)4O6(OAC)3]I5.2H2O.4C4H8O [J].

BHULA, R ;

COLLIER, S ;

ROBINSON, WT ;

WEATHERBURN, DC .

INORGANIC CHEMISTRY, 1990, 29 (20) :4027-4032

[8] STRUCTURALLY DIVERSE MANGANESE(III) SCHIFF-BASE COMPLEXES - CHAINS, DIMERS, AND CAGES [J].

BONADIES, JA ;

KIRK, ML ;

LAH, MS ;

KESSISSOGLOU, DP ;

HATFIELD, WE ;

PECORARO, VL .

INORGANIC CHEMISTRY, 1989, 28 (11) :2037-2044

[9]

BURNETT MN, 1996, ORNL6895 ORTEP

[10] Utilisation of homogeneous and supported chiral metal(salen) complexes in asymmetric catalysis [J].

Canali, L ;

Sherrington, DC .

CHEMICAL SOCIETY REVIEWS, 1999, 28 (02) :85-93

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