Thickness-dependent microstructures and electrical properties of CaCu3Ti4O12 films derived from sol-gel process

被引:26
作者
Chang, Li-Chun
Lee, Dai-Ying [1 ]
Ho, Chia-Cheng [1 ]
Chiou, Bi-Shiou [1 ,2 ]
机构
[1] Natl Chiao Tung Univ, Inst Elect, Hsinchu 30039, Taiwan
[2] Natl Chiao Tung Univ, Innovat Packaging Res Ctr, Hsinchu, Taiwan
关键词
sol-gel; CaCu3Ti4O12 (CCTO); thickness-dependent properties; dielectric;
D O I
10.1016/j.tsf.2007.07.009
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
CaCu3Ti4O12 (CCTO) thin films with various thicknesses were prepared by a sol-gel multiple coating processes on Pt/Ti/SiO2/Si substrates. Microstructures and surface morphologies of CCTO thin films were analyzed by grazing incident X-ray diffractometer (GIXRD) and scanning electron microscope (SEM), respectively. The correlation between the thickness and electrical properties of CCTO films was investigated. The dielectric constants of CCTO films decreased with increasing film thickness (coating cycle). Both the dielectric constant of CCTO films and interlayer are calculated. Possible mechanisms are explored to explain the thickness dependence of the dielectric constant of CCTO films. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:454 / 459
页数:6
相关论文
共 14 条
[1]   Microstructure and dielectric properties of pulsed-laser-deposited CaCu3Ti4O12 thin films on LaNiO3 buffered Pt/Ti/SiO2/Si substrates [J].
Fang, L ;
Shen, M ;
Yao, D .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2005, 80 (08) :1763-1767
[2]   Effects of postanneal conditions on the dielectric properties of CaCu3Ti4O12 thin films prepared on Pt/Ti/SiO2/Si substrates [J].
Fang, L ;
Shen, MR ;
Cao, WW .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (11) :6483-6485
[3]   Deposition and dielectric properties of CaCu3Ti4O12 thin films on Pt/Ti/SiO2/Si substrates using pulsed-laser deposition [J].
Fang, L ;
Shen, MR .
THIN SOLID FILMS, 2003, 440 (1-2) :60-65
[4]   First-principles study of the structure and lattice dielectric response of CaCu3Ti4O12 -: art. no. 214112 [J].
He, LX ;
Neaton, JB ;
Cohen, MH ;
Vanderbilt, D ;
Homes, CC .
PHYSICAL REVIEW B, 2002, 65 (21) :2141121-21411211
[5]  
*JCPDS, 7521888 JCDPS
[6]   Nanocomposite-like structure in an epitaxial CaCu3Ti4O12 film on LaAlO3(001) [J].
Jiang, JC ;
Meletis, EI ;
Chen, CL ;
Lin, Y ;
Zhang, Z ;
Chu, WK .
PHILOSOPHICAL MAGAZINE LETTERS, 2004, 84 (07) :443-450
[7]  
KINGERY WD, 1976, INTRO CERAMICS, P947
[8]   Antiferromagnetism in CaCu3Ti4O12 studied by magnetic Raman spectroscopy [J].
Koitzsch, A ;
Blumberg, G ;
Gozar, A ;
Dennis, B ;
Ramirez, AP ;
Trebst, S ;
Wakimoto, S .
PHYSICAL REVIEW B, 2002, 65 (05) :1-4
[9]   Raman spectroscopy of CaCu3Ti4O12 -: art. no. 132102 [J].
Kolev, N ;
Bontchev, RP ;
Jacobson, AJ ;
Popov, VN ;
Hadjiev, VG ;
Litvinchuk, AP ;
Iliev, MN .
PHYSICAL REVIEW B, 2002, 66 (13)
[10]   Giant dielectric constant response in a copper-titanate [J].
Ramirez, AP ;
Subramanian, MA ;
Gardel, M ;
Blumberg, G ;
Li, D ;
Vogt, T ;
Shapiro, SM .
SOLID STATE COMMUNICATIONS, 2000, 115 (05) :217-220