An unusual abrupt thermal spin-state transition in [FeL2][BF4]2 [L=2,6-di(pyrazol-1-yl)pyridine]

被引：137
|
作者：
Holland, JM
McAllister, JA
Lu, ZB
Kilner, CA
Thornton-Pett, M
Halcrow, MA
机构：
[1] Univ Leeds, Sch Chem, Ctr Self Organising Mol Syst, Leeds LS2 9JT, W Yorkshire, England
[2] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
[3] Univ Cambridge, Interdisciplinary Res Ctr Superconduct, Cambridge CB3 0HE, England
来源：
CHEMICAL COMMUNICATIONS | 2001年 / 06期
关键词：
D O I：
10.1039/b100995h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The complex [Fe((LH)-H-1)(2)][BF4](2) exhibits an abrupt thermal spin-crossover which may be mediated by an order-disorder transition of the BF4- anions.
引用
收藏
页码：577 / 578
页数：2
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