Synthesis and thermodynamics of lead(II), manganese(II), and cobalt(II) pivalate complexes

被引：4
作者：
Dement'ev, A. I. [1 ]
Rodyakina, S. N. [1 ,2 ]
Kayumova, D. B. [2 ]
Kamkin, N. N. [1 ]
Yaryshev, N. G. [1 ]
Alikhanyan, A. S. [2 ]
机构：
[1] Moscow State Pedag Univ, Inst Biol & Chem, Moscow 119435, Russia
[2] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 62卷 / 10期
关键词：
SENSORS; CO3O4;
D O I：
10.1134/S0036023617100060
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Manganese and cobalt oxopivalates and lead pivalate have been synthesized, mass spectral and thermogravimetric analysis have been performed. Sublimation enthalpies of cobalt and manganese oxopivalates have been determined for the first time, while the sublimation enthalpy of lead pivalate has been found to agree well with literature data. Low sublimation enthalpy, high volatility, and monomolecular composition of gas phase allow one to use these complexes as precursors for preparing oxide films and materials by MOCVD method.
引用
收藏
页码：1379 / 1383
页数：5
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