Unravelling chromism in metal-organic frameworks

被引：73

作者：

Mehlana, Gift ^{[1
]}

Bourne, Susan A. ^{[2
]}

机构：

[1] Midlands State Univ, Dept Chem Technol, Fac Sci & Technol, Private Bag 9055 Senga Rd, Gweru, Zimbabwe

[2] Univ Cape Town, Ctr Supramol Chem Res, Dept Chem, ZA-7701 Rondebosch, South Africa

来源：

CRYSTENGCOMM | 2017年 / 19卷 / 30期

基金：

新加坡国家研究基金会;

关键词：

COORDINATION POLYMERS; SINGLE-CRYSTAL; VISIBLE-LIGHT; THIN-FILM; MOFS; ADSORPTION; LIGANDS; BEHAVIOR; NETWORK; DESIGN;

D O I：

10.1039/c7ce00710h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper examines chromic metal-organic frameworks, an important class of materials owing to their applications in several technological fields. These materials change their absorption spectra upon application of an external stimuli such as heat, pressure, light etc. This review explores recent advancements in photochromic, thermochromic, solvatochromic, and piezochromic metal-organic frameworks (MOFs). Emphasis is directed towards the design of chromic MOFs as well as the mechanisms associated with the colour change upon application of an external stimulus. Compared to traditional organic and inorganic materials, MOFs show exceptional chromic behavior as they can be fine-tuned to tailor the desired properties.

引用

页码：4238 / 4259

页数：22

共 90 条

[51] A new class of thermo- and solvatochromic metal-organic frameworks based on 4-(pyridin-4-yl)benzoic acid [J].

Mehlana, Gift ;

Bourne, Susan A. ;

Ramon, Gaelle .

DALTON TRANSACTIONS, 2012, 41 (14) :4224-4231

[52] Mechanized azobenzene-functionalized zirconium metal-organic framework for on-command cargo release [J].

Meng, Xiangshi ;

Gui, Bo ;

Yuan, Daqiang ;

Zeller, Matthias ;

Wang, Cheng .

SCIENCE ADVANCES, 2016, 2 (08)

[53] Rational construction of metal-organic frameworks for heterogeneous catalysis [J].

Ou, Sha ;

Wu, Chuan-De .

INORGANIC CHEMISTRY FRONTIERS, 2014, 1 (10) :721-734

[54] Photochromic organic-inorganic hybrid materials [J].

Pardo, Rosario ;

Zayat, Marcos ;

Levy, David .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (02) :672-687

[55] Copper(I) Coordination Polymers of N,N′-Bis[3-(methylthio)propyl]pyromellitic Diimide: Crystal Transformation and Solvatochromism by Halogen-π Interactions [J].

Park, Garam ;

Yang, Hojin ;

Kim, Tae Ho ;

Kim, Jineun .

INORGANIC CHEMISTRY, 2011, 50 (03) :961-968

[56] Photochromic Metal-Organic Frameworks: Reversible Control of Singlet Oxygen Generation [J].

Park, Jihye ;

Feng, Dawei ;

Yuan, Shuai ;

Zhou, Hong-Cai .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (02) :430-+

[57] Photoresponsive porous materials: the design and synthesis of photochromic diarylethene-based linkers and a metal-organic framework [J].

Patel, Dinesh G. ;

Walton, Ian M. ;

Cox, Jordan M. ;

Gleason, Cody J. ;

Butzer, David R. ;

Benedict, Jason B. .

CHEMICAL COMMUNICATIONS, 2014, 50 (20) :2653-2656

[58] Photoresponsive Host-Guest Functional Systems [J].

Qu, Da-Hui ;

Wang, Qiao-Chun ;

Zhang, Qi-Wei ;

Ma, Xiang ;

Tian, He .

CHEMICAL REVIEWS, 2015, 115 (15) :7543-7588

[59] On/off luminescence vapochromic selective sensing of benzene and its methylated derivatives by a trinuclear silver(I) pyrazolate sensor [J].

Rawashdeh-Omary, Manal A. ;

Rashdan, Maher D. ;

Dharanipathi, Shylaja ;

Elbjeirami, Oussama ;

Ramesh, Prashanth ;

Dias, H. V. Rasika .

CHEMICAL COMMUNICATIONS, 2011, 47 (04) :1160-1162

[60] Metal-organic frameworks: a new class of porous materials [J].

Rowsell, JLC ;

Yaghi, OM .

MICROPOROUS AND MESOPOROUS MATERIALS, 2004, 73 (1-2) :3-14

← 1 2 3 4 5 6 7 8 9 →