Unravelling chromism in metal-organic frameworks

被引：69

作者：

Mehlana, Gift ^{[1
]}

Bourne, Susan A. ^{[2
]}

机构：

[1] Midlands State Univ, Dept Chem Technol, Fac Sci & Technol, Private Bag 9055 Senga Rd, Gweru, Zimbabwe

[2] Univ Cape Town, Ctr Supramol Chem Res, Dept Chem, ZA-7701 Rondebosch, South Africa

来源：

CRYSTENGCOMM | 2017年 / 19卷 / 30期

基金：

新加坡国家研究基金会;

关键词：

COORDINATION POLYMERS; SINGLE-CRYSTAL; VISIBLE-LIGHT; THIN-FILM; MOFS; ADSORPTION; LIGANDS; BEHAVIOR; NETWORK; DESIGN;

D O I：

10.1039/c7ce00710h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper examines chromic metal-organic frameworks, an important class of materials owing to their applications in several technological fields. These materials change their absorption spectra upon application of an external stimuli such as heat, pressure, light etc. This review explores recent advancements in photochromic, thermochromic, solvatochromic, and piezochromic metal-organic frameworks (MOFs). Emphasis is directed towards the design of chromic MOFs as well as the mechanisms associated with the colour change upon application of an external stimulus. Compared to traditional organic and inorganic materials, MOFs show exceptional chromic behavior as they can be fine-tuned to tailor the desired properties.

引用

页码：4238 / 4259

页数：22

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