Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]

被引：33

作者：

Affan, M. A. ^{[1
]}

Salam, M. A. ^{[1
]}

Ahmad, Fasihuddin B. ^{[1
]}

Ismail, J. ^{[1
]}

Shamsuddin, Mustaffa B. ^{[2
]}

Ali, Hapipah M. ^{[3
]}

机构：

[1] Univ Malaysia Sarawak, Fac Resource Sci & Technol, Kota Samarahan 94300, Sarawak, Malaysia

[2] Univ Teknol Malaysia, Dept Chem, Utm Skudai 81310, Johor, Malaysia

[3] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

来源：

INORGANICA CHIMICA ACTA | 2011年 / 366卷 / 01期

关键词：

Substituted thiosemicarbazone; Organotin(IV) complexes; Spectral analyses; Crystal structure; 2-BENZOYLPYRIDINE-DERIVED THIOSEMICARBAZONES; SPECTRAL CHARACTERIZATION; COPPER(II) COMPLEXES; TIN(IV) COMPLEXES; LIGAND; TRI-ORGANOTIN(IV); NICKEL(II); ONS;

D O I：

10.1016/j.ica.2010.11.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2-4) have been synthesized and characterized by CHN analyses, molar conductivity, UV-Vis, FT-IR and H-1 NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) angstrom, b = 9.5970(2) angstrom, c = 9.4353(2) angstrom. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：227 / 232

页数：6

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