Synthesis and spectroscopic characterization of organotin(IV) complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of [PhSnCl2(BPCT)]

被引：33

作者：

Affan, M. A. ^{[1
]}

Salam, M. A. ^{[1
]}

Ahmad, Fasihuddin B. ^{[1
]}

Ismail, J. ^{[1
]}

Shamsuddin, Mustaffa B. ^{[2
]}

Ali, Hapipah M. ^{[3
]}

机构：

[1] Univ Malaysia Sarawak, Fac Resource Sci & Technol, Kota Samarahan 94300, Sarawak, Malaysia

[2] Univ Teknol Malaysia, Dept Chem, Utm Skudai 81310, Johor, Malaysia

[3] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

来源：

INORGANICA CHIMICA ACTA | 2011年 / 366卷 / 01期

关键词：

Substituted thiosemicarbazone; Organotin(IV) complexes; Spectral analyses; Crystal structure; 2-BENZOYLPYRIDINE-DERIVED THIOSEMICARBAZONES; SPECTRAL CHARACTERIZATION; COPPER(II) COMPLEXES; TIN(IV) COMPLEXES; LIGAND; TRI-ORGANOTIN(IV); NICKEL(II); ONS;

D O I：

10.1016/j.ica.2010.11.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2-4) have been synthesized and characterized by CHN analyses, molar conductivity, UV-Vis, FT-IR and H-1 NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) angstrom, b = 9.5970(2) angstrom, c = 9.4353(2) angstrom. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：227 / 232

页数：6

共 28 条

[1]

Affan MA, 2007, INDIAN J CHEM A, V46, P1063

[2]

Affan MA, 2009, INDIAN J CHEM A, V48, P1388

[3]

Affan M.A., 2009, J. Sci. Res., V1, P306, DOI [10.1080/00958972.2011.590193, DOI 10.1080/00958972.2011.590193]

[4] Synthesis and characterization of copper(II) complexes of 4-alkyl/aryl-1,2-naphthoquinones thiosemicarbazones derivatives as potent DNA cleaving agents [J].

Afrasiabi, Z ;

Sinn, E ;

Kulkarni, PP ;

Ambike, V ;

Padhye, S ;

Deobagakar, D ;

Heron, M ;

Gabbutt, C ;

Anson, CE ;

Powell, AK .

INORGANICA CHIMICA ACTA, 2005, 358 (06) :2023-2030

[5] Chlorodiphenyltin(IV) piperidine-1-carbodithioate [J].

Ali, S ;

Ahmad, SU ;

Sadiq-ur-Rehman ;

Shahzadi, S ;

Parvez, M ;

Mazhar, M .

APPLIED ORGANOMETALLIC CHEMISTRY, 2005, 19 (01) :200-200

[6] Synthesis, crystal structure and characterization of 3-thiophene aldehyde thiosemicarbazone and its complexes with cobalt(II), nickel(II) and copper(II) [J].

Alomar, Kusai ;

Khan, Mustayeen A. ;

Allain, Magali ;

Bouet, Gilles .

POLYHEDRON, 2009, 28 (07) :1273-1280

[7]

Armarego W.L. F., 1996, PURIFICATION LAB CHE, V4th

[8] Synthesis, characterization, cytotoxic activity and crystal structures of tri- and di-organotin(IV) complexes constructed from the β-{[(E)-1-(2-hydroxyaryl)alkylidene]amino}propionate and β-{[(2Z)-(3-hydroxy-1-methyl-2-butenylidene)]amino}propionate skeletons [J].

Baul, TSB ;

Masharing, C ;

Basu, S ;

Rivarola, E ;

Holcapek, M ;

Jirásko, R ;

Lycka, A ;

de Vos, D ;

Linden, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2006, 691 (05) :952-965

[9] Synthesis, characterization and hydrolytic behavior of new bis (2-pyridylthio) acetate ligand and related organotin(IV) complexes [J].

Benetollo, F ;

Lobbia, GG ;

Mancini, M ;

Pellei, M ;

Santini, C .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (08) :1994-2001

[10] The crystal structure and hydrolysis equilibrium of triphenyl(2-mercapto-1-methylimidazolato)tin(IV) [J].

Casas, JS ;

Castineiras, A ;

Martinez, EG ;

Gonzalez, AS ;

Sanchez, A ;

Sordo, J .

POLYHEDRON, 1997, 16 (05) :795-800

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