A complete 4fn energy level diagram for all trivalent lanthanide ions

被引：115

作者：

Peijzel, PS

Meijerink, A

Wegh, RT

Reid, MF

Burdick, GW

机构：

[1] Univ Utrecht, Debye Inst, Dept Condensed Matter & Interfaces, NL-3508 TA Utrecht, Netherlands

[2] Univ Canterbury, Dept Phys & Astron, Christchurch 1, New Zealand

[3] Andrews Univ, Dept Phys, Berrien Springs, MI 49104 USA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2005年 / 178卷 / 02期

关键词：

lanthanide; spectroscopy; VUV; energy levels; carnall;

D O I：

10.1016/j.jssc.2004.07.046

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We describe the calculations of the 4f(n) energy levels, reduced matrix elements for 4f(n)-4f(n) transitions and the simulation of absorption and emission spectra. A complete 4f(n) energy level diagram is calculated for all trivalent lanthanide ions in LaF3. The calculated energy levels are compared with experimentally obtained energies. For Ce, Pr, Nd, Eu, Gd, Ho, Er, Tm and Yb many, and in some cases all, energy levels have been observed. This work provides a starting point for future investigation of as yet unobserved VUV energy levels. (c) 2004 Elsevier Inc. All rights reserved.

引用

页码：448 / 453

页数：6

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