Conducting composites of polythiophene and polyfuran with acetylene black

被引：33

作者：

Ballav, N ^{[1
]}

Biswas, M ^{[1
]}

机构：

[1] Presidency Coll, Dept Chem, Kolkata 73, W Bengal, India

来源：

POLYMER INTERNATIONAL | 2005年 / 54卷 / 04期

关键词：

polythiophene; polyfuran; acetylene black; nanocomposite; thermal stability; conductivity;

D O I：

10.1002/pi.1767

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Conducting composites of polythiophene (PTP) and polyfuran (PF) with acetylene black (AB) were prepared via chemical oxidative polymerization of thiophene and furan in a suspension of AB in CHCl3 at room temperature using anhydrous FeCl3 as the oxidant. Formation of PTP and PF and their subsequent incorporation in PTP-AB and PF-AB composite systems were confirmed by FTIR analysis. Scanning electron microscope analysis showed the presence of compact clusters of particles in both composites. Transmission electron micrographs of PTP-AB and PF-AB composites showed formation of globular polymer encapsulated AB particles with average diameters of the order of similar to100 nm in both systems. Thermogravimetric analysis revealed that the overall thermal stability varied in the order: AB > PTP-AB > PTP and AB > PF-AB > PF. DC conductivity values for the PTP-AB and PF-AB composites were of the order of 10(-2) and 10(-3) S cm(-1), respectively. (C) 2004 Society of Chemical Industry.

引用

页码：725 / 729

页数：5

共 24 条

[21]

MURATA H, 1993, 65 APR M CHEM SOC JA, V140, P244

[22] CONJUGATED POLY(THIOPHENES) - SYNTHESIS, FUNCTIONALIZATION, AND APPLICATIONS [J].

RONCALI, J .

CHEMICAL REVIEWS, 1992, 92 (04) :711-738

[23] DIRECT SYNTHESIS OF CONDUCTING POLYMERS FROM SIMPLE MONOMERS [J].

TOSHIMA, N ;

HARA, S .

PROGRESS IN POLYMER SCIENCE, 1995, 20 (01) :155-183

[24] ELECTROCHEMICAL SYNTHESIS AND CHARACTERIZATION OF POLYCONJUGATED POLYFURAN [J].

ZOTTI, G ;

SCHIAVON, G ;

COMISSO, N ;

BERLIN, A ;

PAGANI, G .

SYNTHETIC METALS, 1990, 36 (03) :337-351

← 1 2 3 →