In-situ synthesis of nickel modified molybdenum carbide catalyst for dry reforming of methane

被引：84

作者：

Zhang, Anjie ^{[1
,2
]}

Zhu, Aimin ^{[2
]}

Chen, Bingbing ^{[1
,2
]}

Zhang, Shaohua ^{[1
,2
]}

Au, Chaktong ^{[3
]}

Shi, Chuan ^{[1
,2
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian, Peoples R China

[2] Dalian Univ Technol, Lab Plasma Phys Chem, Dalian, Peoples R China

[3] Hong Kong Baptist Univ, Dept Chem, Hong Kong, Hong Kong, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2011年 / 12卷 / 09期

基金：

中国国家自然科学基金;

关键词：

In-situ synthesis; Methane; Carbon dioxide; Molybdenum carbide; Reforming; SYNTHESIS GAS; TUNGSTEN CARBIDE;

D O I：

10.1016/j.catcom.2011.01.019

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ni-Mo2C catalyst has been in-situ synthesized through carburization of NiMoOx in methane and carbon dioxide feed gas for dry reforming of methane (DRM) at atmospheric pressure. Characterization and evaluation results indicated that the Ni-Mo2C catalyst is superior to the traditional metal carbide catalysts in the DRM process. XRD and TPR results showed that the addition of nickel had a positive effect on the in-situ formation of Mo2C. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：803 / 807

页数：5

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