X-Ray Detected Magnetic Hysteresis of Thermally Evaporated Terbium Double-Decker Oriented Films

被引:112
作者
Margheriti, Ludovica [1 ,2 ]
Chiappe, Daniele [3 ,4 ]
Mannini, Matteo [1 ,2 ]
Car, Pierre-E [1 ,2 ]
Sainctavit, Philippe [5 ]
Arrio, Marie-Anne [5 ]
de Mongeot, Francesco Buatier [3 ,4 ]
Cezar, Julio C. [6 ]
Piras, Federica M. [7 ]
Magnani, Agnese [7 ]
Otero, Edwige [8 ]
Caneschi, Andrea [1 ,2 ]
Sessoli, Roberta [1 ,2 ]
机构
[1] Univ Florence, Dept Chem, INSTM Res Unit, I-50019 Sesto Fiorentino, FI, Italy
[2] ISTM CNR, I-50019 Sesto Fiorentino, FI, Italy
[3] Univ Genoa, Dept Phys, I-16146 Genoa, Italy
[4] CNISM, I-16146 Genoa, Italy
[5] Univ Paris 06, Inst Mineral & Phys Milieux Condenses, UMR 7590, F-75252 Paris 5, France
[6] European Synchrotron Radiat Facil, F-38043 Grenoble, France
[7] Univ Siena, Dept Pharmaceut & Appl Chem, I-53100 Siena, Italy
[8] Synchrotron Soleil, F-91192 Gif Sur Yvette, France
关键词
SINGLE-MOLECULE MAGNETS; THIN-FILMS; ABSORPTION-SPECTRA; DICHROISM; DEPOSITION;
D O I
10.1002/adma.201003275
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The successful evaporation of thick and thin films of an intact bis(phthalocyaninato)terbium single molecule magnet is reported and confirmed by chemical and magnetic characterization techniques. Synchrotron-based X-ray absorption spectroscopy reveals different magnetization dynamics associated to a change in the orientation of the molecules depending on the thickness of the films.
引用
收藏
页码:5488 / 5493
页数:6
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