A neutral triangular supramolecule formed by Mo24+ units

被引：89
作者：
Cotton, FA
Lin, C
Murillo, CA
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
[2] Texas A&M Univ, Mol Struct & Bonding Lab, College Stn, TX 77842 USA
[3] Univ Costa Rica, Dept Chem, San Jose, Costa Rica
来源：
INORGANIC CHEMISTRY | 2001年 / 40卷 / 03期
关键词：
D O I：
10.1021/ic000963z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of [cis-Mo-2(DAniF)(2)(CH3CN)(4)](BF4)(2), DAniF = N,N'-di-p-anisylformamidinate, and ((Bu4N)-N-n)(2)(trans-1,4-cyclohexanedicarboxylate) gives the first neutral molecular triangle derived from quadruply bonded dimolybdenum units.
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页码：575 / +
页数：4
相关论文
共 35 条
[1]   High-nuclearity metal-cyanide clusters:: Assembly of a Cr8Ni6(CN)24 cage with a face-centered cubic geometry [J].
Berseth, PA ;
Sokol, JJ ;
Shores, MP ;
Heinrich, JL ;
Long, JR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (40) :9655-9662
[2]   Self assembly of a diphenanthrolinylpyrene-bridged CuI trimer [J].
Bonnefous, C ;
Bellec, N ;
Thummel, RP .
CHEMICAL COMMUNICATIONS, 1999, (13) :1243-1244
[3]  
*BRUK AN INSTR DIV, 1997, SAINT V5 06 SOFTW CC
[4]  
*BRUK AN INSTR DIV, 1998, SMART V5 5 SOFTW CCD
[5]   Compounds in which the Mo24+ unit is embraced by one, two or three formamidinate ligands together with acetonitrile ligands [J].
Chisholm, MH ;
Cotton, FA ;
Daniels, LM ;
Folting, K ;
Huffman, JC ;
Iyer, SS ;
Lin, C ;
Macintosh, AM ;
Murillo, CA .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (09) :1387-1391
[6]  
Cotton F.A., 1993, MULTIPLE BONDS METAL
[7]   Supramolecular structures based on dimetal units: simultaneous utilization of equatorial and axial connections [J].
Cotton, FA ;
Lin, C ;
Murillo, CA .
CHEMICAL COMMUNICATIONS, 2001, (01) :11-12
[8]   Square and triangular arrays based on Mo24+ and Rh24+ units [J].
Cotton, FA ;
Daniels, LM ;
Lin, C ;
Murillo, CA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (18) :4538-4539
[9]  
Cotton FA, 1999, CHEM COMMUN, P841
[10]  
COTTON FA, IN PRESS INORG CHEM
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