Intercalation Reactions of Layered Manganese(III,IV) Oxides

被引：8

作者：

Ammundsen, Brett ^{[1
]}

Wortham, Etienne ^{[1
]}

Jones, Deborah J. ^{[1
]}

Roziere, Jacques ^{[1
]}

机构：

[1] Univ Montpellier 2, CNRS, Lab Agregats Mol & Mat Inorgan, ESA 5072, F-34095 Montpellier 5, France

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1998年 / 311卷

关键词：

manganese oxide; birnessite; alkylammonium intercalates; polyaniline; nanocomposite electrode materials;

D O I：

10.1080/10587259808042406

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Layered hydrated birnessite-type manganese oxides have been intercalated with n-alkylammonium ions by ion-exchange for interlayer sodium or potassium, and by acid-base reactions. The expanded phases have modified interlayer environments and can be used as precursors for intercalation of aniline, which is oxidised and polymerised between the layers.

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收藏

页码：327 / 332

页数：6

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