Structure determination of gaseous metal and semi-metal cluster ions by ion mobility spectrometry

被引:49
|
作者
Weis, P [1 ]
机构
[1] Univ Karlsruhe, Inst Phys Chem, D-76128 Karlsruhe, Germany
关键词
metal; cluster; ion; mobility;
D O I
10.1016/j.ijms.2005.06.005
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
Gas phase ion mobility spectrometry in combination with quantum chemical calculations has proven to be extremely useful for the structure determination of cluster ions. After a short introduction into the methodology, investigations focused on clusters of different main group metals and semi-metals are reviewed. Based on the findings of different groups, it became apparent that in many cases small clusters (below 100 atoms) show a rich variation in shape as function of the number of atoms. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 13
页数:13
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