Thermochemical Properties of Binary Ba-In Alloys

被引:1
|
作者
Shevchenko, M. A. [1 ]
Kudin, V. G. [2 ]
Ivanov, M. I. [1 ]
Berezutskii, V. V.
Sudavtsova, V. S. [1 ]
机构
[1] Natl Acad Sci Ukraine, Frantsevich Inst Problems Mat Sci, Kiev, Ukraine
[2] Taras Shevchenko Natl Univ, Kiev, Ukraine
关键词
thermodynamic activity; melt; barium; indium; calorimetry method; ideal associated solution model; CA-IN; MAGNESIUM; SYSTEMS; CA8IN3;
D O I
10.1007/s11106-018-9928-6
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The thermochemical properties of binary Ba-In melts were studied using calorimetry at 1070-1320 K over a wide composition range. It is shown that these melts are characterized by significant exothermic heat effects of mixing. The ideal associated solution model was used to calculate the activities of components, Gibbs energies, and mixing entropies of the alloys and to construct the liquidus curve in the phase diagram. These parameters agree with the literature data.
引用
收藏
页码:556 / 566
页数:11
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