Photoelectrochemical characterization of nearly monodisperse CdS nanoparticles-immobilized gold electrodes

被引：35

作者：

Miyake, M

Torimoto, T

Sakata, T

Mori, H

Yoneyama, H

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan

[2] Osaka Univ, Res Ctr Ultra High Voltage Elect Microscopy, Suita, Osaka 5650871, Japan

来源：

LANGMUIR | 1999年 / 15卷 / 04期

关键词：

D O I：

10.1021/la980975l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Several kinds of nearly monodisperse size-quantized CdS particles (Q-CdS) capped with 2-aminoethanethiol were prepared by means of size selective photoetching and were covalently immobilized onto a gold electrode substrate coated previously with a self-assembled monolayer of 2-aminoethanethiol. The potential of the conduction band edge of Q-CdS estimated from the onset potential of photocurrents was negatively shifted with a decrease in the diameter of CdS nanoparticles, the results being in good accord with the theoretical prediction.

引用

收藏

页码：1503 / 1507

页数：5

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