New strategy for controlling the oligothiophene aggregation mode utilizing the gel-to-sol phase transition induced by crown-alkali metal interactions

被引:40
作者
Sobczuk, Adam A. [1 ]
Tamaru, Shun-ichi [1 ]
Shinkai, Seiji [1 ,2 ]
机构
[1] Sojo Univ, Dept Nanosci, Kumamoto 8600082, Japan
[2] Inst Syst Informat Technol & Nanotechnol, Nanotechnol Lab, Nishi Ku, Fukuoka 8190385, Japan
关键词
ION RECOGNITION; ALLOSTERIC BINDING; MOLECULAR DESIGN; ETHERS; POLYMERS; GELATORS; ORGANIZATION; ORGANOGELS; GUEST; HOST;
D O I
10.1039/c1cc00026h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new functional low molecular-weight gelator (LMWG) based on crown-appended quaterthiophene was synthesized and investigated as a new alkali metal cation responsive material with enhanced fluorescence emission upon gel-to-sol phase transition.
引用
收藏
页码:3093 / 3095
页数:3
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