Mild and efficient TBAI-catalyzed synthesis of 1,2,3-benzotriazine-4-(3H)-ones from tert-butyl nitrite and 2-aminobenzamides under acid-free conditions

被引：23

作者：

Yan, Yizhe ^{[1
,2
]}

Li, Hongyi ^{[1
]}

Niu, Bin ^{[1
]}

Zhu, Changrui ^{[1
]}

Chen, Ting ^{[1
]}

Liu, Yanqi ^{[1
]}

机构：

[1] Zhengzhou Univ Light Ind, Sch Food & Biol Engn, Zhengzhou 450000, Peoples R China

[2] Collaborat Innovat Ctr Food Prod & Safety, Zhengzhou, Henan Province, Peoples R China

来源：

TETRAHEDRON LETTERS | 2016年 / 57卷 / 37期

关键词：

1,2,3-Benzotriazine-4-(3H)-ones; tert-Butyl nitrite; 2-Aminobenzamides; Tetrabutylammonium iodide; Acid-free; TEMPO; (BUONO)-BU-T; DERIVATIVES; NITRATION; ALKYNES; ACCESS;

D O I：

10.1016/j.tetlet.2016.07.102

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A facile and efficient annulation of 2-aminobenzamides and tert-butyl nitrite was developed, affording 1,2,3-benzotriazine-4-(3H)-ones in good yields under mild conditions. Notably, the reaction was carried out in the absence of strong acid and tert-butyl nitrite was employed as the nitrogen source. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：4170 / 4173

页数：4

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