Catalytic Hydroarylation of Alkenes with Phenols using B(C6F5)3

被引：25

作者：

Bentley, Jordan N. ^{[1
]}

Caputo, Christopher B. ^{[1
]}

机构：

[1] York Univ, Dept Chem, 4700 Keele St, Toronto, ON M3J 1P3, Canada

来源：

ORGANOMETALLICS | 2018年 / 37卷 / 21期

基金：

加拿大自然科学与工程研究理事会;

关键词：

C-O; ACID; CYCLOISOMERIZATION; HYDROALKOXYLATION; ALKYLATION; HYDROTHIOLATION; HYDROAMINATION; HYDROGENATION; DERIVATIVES; ADDUCTS;

D O I：

10.1021/acs.organomet.8b00621

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We demonstrate that tris(pentafluorophenyOborane, B (C6F5)(3), is shown to be an effective catalyst for the hydroarylation of olefins to yield substituted phenols. This system features fast reaction times, mild conditions, and good yields for a select scope of olefinic substrates and various phenols, resulting in C-C bond formation. Experimental data support two possible mechanisms, where the Lewis acid can activate either the olefin or the phenol as the first step in the catalytic mechanism.

引用

页码：3654 / 3658

页数：5

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