Direct coordination of metal ions to cucurbit[n]urils

被引：38

作者：

Cong Hang ^{[1
]}

Zhu QianJiang ^{[1
]}

Xue SaiFeng ^{[1
]}

Tao Zhu ^{[1
]}

Wei Gang ^{[2
]}

机构：

[1] Guizhou Univ, Key Lab Macrocycl & Supramol Chem Guizhou Prov, Guiyang 550025, Peoples R China

[2] CSIRO Mat Sci & Engn, Lindfield, NSW 2070, Australia

来源：

CHINESE SCIENCE BULLETIN | 2010年 / 55卷 / 32期

基金：

中国国家自然科学基金;

关键词：

metal ions; cucurbit[n]urils; direct coordination; molecular capsules; tubular polymers; molecular bracelets; CHARGE-TRANSFER INTERACTIONS; RIGID-ROD MOLECULES; MACROCYCLIC CAVITAND; COMPLEXED CUCURBITURIL; CRYSTAL-STRUCTURE; SUPRAMOLECULAR ASSEMBLIES; BUILDING-BLOCKS; COPPER(II) COMPLEXES; LANTHANIDE COMPLEXES; PERRHENATE LIGANDS;

D O I：

10.1007/s11434-010-4146-8

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Cucurbit[n]urils (Q[n]) are promising ligands for the coordination of metal ions, metal complexes or clusters, and form various Q[n]-based complexes. Among the Q[n] complexes, those formed by direct coordination between Q[n]s and metal ions are particularly important. The direct coordination of metal ions to cucurbit[n]urils leads to the formation of Q[n]-based molecular capsules, tubular polymers and molecular bracelets, which could have nanoscale applications in drug delivery, molecular devices and new materials.

引用

页码：3633 / 3640

页数：8

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