Direct coordination of metal ions to cucurbit[n]urils

被引：38

作者：

Cong Hang ^{[1
]}

Zhu QianJiang ^{[1
]}

Xue SaiFeng ^{[1
]}

Tao Zhu ^{[1
]}

Wei Gang ^{[2
]}

机构：

[1] Guizhou Univ, Key Lab Macrocycl & Supramol Chem Guizhou Prov, Guiyang 550025, Peoples R China

[2] CSIRO Mat Sci & Engn, Lindfield, NSW 2070, Australia

来源：

CHINESE SCIENCE BULLETIN | 2010年 / 55卷 / 32期

基金：

中国国家自然科学基金;

关键词：

metal ions; cucurbit[n]urils; direct coordination; molecular capsules; tubular polymers; molecular bracelets; CHARGE-TRANSFER INTERACTIONS; RIGID-ROD MOLECULES; MACROCYCLIC CAVITAND; COMPLEXED CUCURBITURIL; CRYSTAL-STRUCTURE; SUPRAMOLECULAR ASSEMBLIES; BUILDING-BLOCKS; COPPER(II) COMPLEXES; LANTHANIDE COMPLEXES; PERRHENATE LIGANDS;

D O I：

10.1007/s11434-010-4146-8

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Cucurbit[n]urils (Q[n]) are promising ligands for the coordination of metal ions, metal complexes or clusters, and form various Q[n]-based complexes. Among the Q[n] complexes, those formed by direct coordination between Q[n]s and metal ions are particularly important. The direct coordination of metal ions to cucurbit[n]urils leads to the formation of Q[n]-based molecular capsules, tubular polymers and molecular bracelets, which could have nanoscale applications in drug delivery, molecular devices and new materials.

引用

页码：3633 / 3640

页数：8

共 85 条

[1] ASSEMBLY OF PORPHYRIN BUILDING-BLOCKS INTO NETWORK STRUCTURES WITH LARGE CHANNELS [J].

ABRAHAMS, BF ;

HOSKINS, BF ;

MICHAIL, DM ;

ROBSON, R .

NATURE, 1994, 369 (6483) :727-729

[2] Synthesis and crystal structure of cucurbit[6]uril adduct of hydrogen-bonded cluster complex [Mo3(μ3-Se)(μ2-O)3(H2O)6Cl3]+ [J].

Abramov, Pavel A. ;

Sokolov, Maxim N. ;

Virovets, Alexander V. ;

Peresypkina, Eugenia V. ;

Fedin, Vladimir P. .

JOURNAL OF CLUSTER SCIENCE, 2007, 18 (03) :597-605

[3] Synthesis, Reactivity, and Kinetics of Substitution in W3PdSe4 Cuboidal Clusters. A Reexamination of the Kinetics of Substitution of the Related W3S4 Cluster with Thiocyanate [J].

Algarra, Andres G. ;

Sokolov, Maxim N. ;

Gonzalez-Platas, Javier ;

Jesus Fernandez-Trujillo, Maria ;

Basallote, Manuel G. ;

Hernandez-Molina, Rita .

INORGANIC CHEMISTRY, 2009, 48 (08) :3639-3649

[4] Improving the properties of organic dyes by molecular encapsulation [J].

Arunkumar, E ;

Forbes, CC ;

Smith, BD .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2005, 2005 (19) :4051-4059

[5]

Beer PD, 2001, ANGEW CHEM INT EDIT, V40, P486, DOI 10.1002/1521-3773(20010202)40:3<486::AID-ANIE486>3.0.CO

[6]

2-P

[7]

Behrend R, 1905, LIEBIGS ANN CHEM, V339, P1

[8] Metal-organic anion receptors: Arranging urea hydrogen-bond donors to encapsulate sulfate ions [J].

Bondy, CR ;

Gale, PA ;

Loeb, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (16) :5030-5031

[9] Cooperative Metal Ion Binding to a Cucurbit[7]uril-Thioflavin T Complex: Demonstration of a Stimulus-Responsive Fluorescent Supramolecular Capsule [J].

Choudhury, Sharmistha Dutta ;

Mohanty, Jyotirmayee ;

Pal, Haridas ;

Bhasikuttan, Achikanath C. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (04) :1395-1401

[10] Supramolecular compounds of chloroaquacomplexes [Mo3Q4(H2O)9-x Clx](4-x) plus (Q = S, Se; x=2, 3, 5) with cucurbit[n]urils [J].

Chubarova, E. V. ;

Sokolov, M. N. ;

Samsonenko, D. G. ;

Vicent, C. ;

Fedin, V. P. .

JOURNAL OF STRUCTURAL CHEMISTRY, 2006, 47 (05) :939-945

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