Halogen bonding driven self-assembly of fluorocarbons and hydrocarbons

被引：67
|
作者：
Metrangolo, P
Pilati, T
Resnati, G
Stevanazzi, A
机构：
[1] Politecn Milan, Dept Chem, I-20131 Milan, Italy
[2] Univ Milan, CNR, Inst Mol Sci & Technol, I-20133 Milan, Italy
来源：
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE | 2003年 / 8卷 / 03期
关键词：
supramolecular chemistry; halogen bonding; donor-acceptor complexes; fluorine;
D O I：
10.1016/S1359-0294(03)00055-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Halogen bonding, the interaction between halogen atoms and lone pair possessing atoms, overcomes the low affinity existing between perfluorocarbon and hydrocarbon derivatives. This interaction effectively drives the self-assembly of materials wherein perfluorocarbon and hydrocarbon layers alternate thanks to a remarkable module segregation. The approach has been exploited in supramolecular polymer coating. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码：215 / 222
页数：8
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