Simulation of the inhibition of hydrogen-air flame propagation

被引:10
作者
Azatyan, V. V. [1 ]
Andrianova, Z. S. [2 ]
Ivanova, A. N. [2 ]
机构
[1] Russian Acad Sci, Inst Struct Macrokinet & Mat Res Problems, Chernogolovka 142432, Moscow Oblast, Russia
[2] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Oblast, Russia
基金
俄罗斯基础研究基金会;
关键词
Flame Propagation; Chain Termination; Flame Speed; Incident Shock Wave; Combus Tion;
D O I
10.1134/S0023158410040014
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The results of simulation and experimental data presented here demonstrate that the competition between chain branching and chain termination is the key factor in hydrogen-air flame propagation, including the temperature regime of the process and the formation of concentration limits. Self-heating becomes significant in developed combustion. It enhances the chain avalanche and ensures the temperature necessary for layer-by-layer chain ignition. By varying the ratio between the chain branching and termination rates by means of an inhibitor makes it possible to control the flame propagation process.
引用
收藏
页码:461 / 468
页数:8
相关论文
共 45 条
[1]   Effect of the molecular structure of olefin admixtures on the combustion and explosion of hydrogen-air mixtures [J].
Avetisyan, A. A. ;
Azatyan, V. V. ;
Kalachev, V. I. ;
Masalova, V. V. ;
Piloyan, A. A. .
KINETICS AND CATALYSIS, 2007, 48 (01) :8-16
[2]  
[Азатян В.В. Azatyan V.V.], 2005, [Кинетика и катализ, Kinetika i kataliz], V46, P835
[3]   The thermal explosion of the detonating mixture is impossible without a chain avalanche [J].
Azatyan, V. V. ;
Baklanov, D. I. ;
Bolod'yan, I. A. ;
Vedeshkin, G. K. ;
Ivanova, A. N. ;
Naboko, I. M. ;
Rubtsov, N. M. ;
Shebeko, Yu. N. .
KINETICS AND CATALYSIS, 2009, 50 (02) :162-167
[4]  
Azatyan V.V., 2004, DOKL ROSS AKAD NAUK, V394, P61
[5]  
Azatyan V.V., 1988, KHIM FIZ, V7, P821
[6]  
AZATYAN VV, 2003, ZH FIZ KHIM, V72, P449
[7]  
AZATYAN VV, 2001, TYAZHELOE MASHINOSTR, P40
[8]  
AZATYAN VV, 1999, KINET KATAL, V40, P818
[9]  
AZATYAN VV, 2008, KHIM FIZ, V27, P93
[10]  
AZATYAN VV, 2002, ZH FIZ KHIM, V76, P775