Chiral ketone-catalyzed asymmetric epoxidation of olefins

被引：1

作者：

Frohn, M ^{[1
]}

Shi, Y ^{[1
]}

机构：

[1] Colorado State Univ, Dept Chem, Ft Collins, CO 80523 USA

来源：

SYNTHESIS-STUTTGART | 2000年 / 14期

关键词：

asymmetric epoxidation; chiral dioxirane; chiral ketone; epoxide; hydrogen peroxide; oxone; potassium peroxymonosulfate;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dioxiranes are remarkably versatile oxidizing agents that show encouraging potential for asymmetric synthesis, particularly asymmetric epoxidation of unfunctionalized olefins. This review outlines the recent development in this area. Discussions are focused on the structural requirements of the chiral ketone catalysts, how structural changes effect the reactivity and selectivity of the catalyst, reaction conditions, and transition states.

引用

页码：1979 / 2000

页数：22

共 64 条

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