A porphyrin-hexa-peri-hexabenzocoronene-porphyrin triad: synthesis, photophysical properties and performance in a photovoltaic device

被引：59

作者：

Wong, Wallace W. H. ^{[1
]}

Khoury, Tony ^{[2
]}

Vak, Doojin ^{[1
]}

Yan, Chao ^{[1
]}

Jones, David J. ^{[1
]}

Crossley, Maxwell J. ^{[2
]}

Holmes, Andrew B. ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Inst Bio21, Parkville, Vic 3010, Australia

[2] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2010年 / 20卷 / 33期

基金：

澳大利亚研究理事会;

关键词：

HETEROJUNCTION SOLAR-CELLS; FIELD-EFFECT TRANSISTORS; ORGANIZATION; MORPHOLOGY; DENDRIMERS; GRAPHENES;

D O I：

10.1039/c0jm00311e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hexa-peri-hexabenzocoronene (HBC) is a discotic polycyclic aromatic hydrocarbon with good charge transport characteristics while the light harvesting property of porphyrins is well-known. In order to take advantage of the properties of both materials, a porphyrin-hexa-peri-hexabenzocoronene-porphyrin triad 6 was synthesised for the first time. In photoluminescence studies, the emission from the higher energy HBC unit was completely quenched by the porphyrin unit indicating efficient energy transfer. This novel hybrid material 6 was tested in bulk heterojunction photovoltaic devices reaching a power conversion efficiency of 1.2%.

引用

页码：7005 / 7014

页数：10

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