Crystal structure of Na4HP3O10 center dot H2O

被引：1

作者：

Kindler, N ^{[1
]}

Jansen, M ^{[1
]}

机构：

[1] UNIV BONN,INST ANORGAN CHEM,D-53121 BONN,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1997年 / 623卷 / 01期

关键词：

tetrasodium triphosphate monohydrate; preparation; crystal structure;

D O I：

10.1002/zaac.19976230109

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Na4HP3O10. H2O crystallizes orthorhombic in space group Pbcn with a = 693.2(5) pm, b = 1203.3(4) pm, c = 1188.5(4) pm; Z = 4. The obtained X-ray diffraction data (9268 symmetrical independent reflections, R=0.047) allowed to locate and refine all the hydrogen atoms. The structure of Na4HP3O10. H2O contains alternating layers of triphosphate anions and sodium cations. The triphosphate ions have site symmetry Ct and are linked by strong oxygen-hydrogen bonds (244pm). The results of thermochemical analyses as well as the vibrational spectrum and data of P-31 MAS-NMR are submitted.

引用

页码：55 / 58

页数：4

共 17 条

[1] CRYSTAL-STRUCTURE OF ACID ALUMINUM AMMONIUM TRIPOLYPHOSPHATE, ALNH4HP3O10
AVERBUCHPOUCHOT, MT
DURIF, A
GUITEL, JC
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (MAY13): : 1436 - 1438
[2] CRYSTAL-STRUCTURE OF ACID ZINC TRIPOLYPHOSPHATE HEXAHYDRATE, ZN2HP3O10.6H2O
AVERBUCHPOUCHOT, MT
GUITEL, JC
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1976, 32 (JUN15): : 1670 - 1673
[3] BOULLE A, 1957, CR HEBD ACAD SCI, V245, P1928
[4] THE CRYSTAL STRUCTURE OF SODIUM TRIPHOSPHATE, NA5P3O10, PHASE-I
CORBRIDGE, DEC
[J]. ACTA CRYSTALLOGRAPHICA, 1960, 13 (03): : 263 - 269
[5] REFINEMENTS OF STRUCTURES CONTAINING BONDS BETWEEN SI P S OR CL + O OR N .3. NA5P3O10 PHASE2
CRUICKSHANK, DWJ
[J]. ACTA CRYSTALLOGRAPHICA, 1964, 17 (06): : 674 - &
[6] THE CRYSTAL STRUCTURE OF SODIUM TRIPHOSPHATE, NA5P3O10 PHASE-II
DAVIES, DR
CORBRIDGE, DEC
[J]. ACTA CRYSTALLOGRAPHICA, 1958, 11 (05): : 315 - 319
[7] Concerning a acid natrium poly-phosphate
Huber, H
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1936, 230 (1/2): : 123 - 128
[8] HUNDT R, 1979, KPLOT PROGRAMM ZEICH
[9] JOHNSON CK, 1970, ORTEP
[10] *JOINT COM POWD DI, 14513 JOINT COM POWD

← 1 2 →