A general strategy for the facile synthesis of 2,7-dibromo-9-heterofluorenes

被引:95
作者
Chen, RF [1 ]
Fan, QL [1 ]
Zheng, C [1 ]
Huang, W [1 ]
机构
[1] Fudan Univ, Inst Adv Mat, Shanghai 200433, Peoples R China
关键词
D O I
10.1021/ol0524499
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A facile, highly efficient, and economical procedure for the preparation of 6,6 '-diiodo-4,4 '-dibromo-3,3 '-dimethoxylbiphenyl has been found. From this compound, a general synthetic strategy for the preparation of 2,7-dibromo-9-heterofluorenes has been developed. Five 2,7-dibromo-9-heterofluorenes have been easily synthesized for the first time according to the procedure presented, opening the door to new classes of inorganic and organometallic conjugated polymeric materials of polyheterofluorenes.
引用
收藏
页码:203 / 205
页数:3
相关论文
共 15 条
[1]   Rigid-core oligothiophene-S,S-dioxides with high photoluminescence efficiencies both in solution and in the solid state [J].
Barbarella, G ;
Favaretto, L ;
Sotgiu, G ;
Antolini, L ;
Gigli, G ;
Cingolani, R ;
Bongini, A .
CHEMISTRY OF MATERIALS, 2001, 13 (11) :4112-4122
[2]  
Brière JF, 2004, J PHYS CHEM B, V108, P3123, DOI 10.1021/jp035363a
[3]   SUBSTITUTION REACTIONS OF 3,3'-DIMETHOXYBIPHENYL [J].
CAMPBELL, N ;
SCOTT, AH .
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1966, (11) :1050-&
[4]   CONDENSED CYCLOBUTANE AROMATIC SYSTEMS .1. THE SYNTHESIS OF 1,2-BENZOBIPHENYLENE AND 1,2-BINAPHTHYLENE [J].
CAVA, MP ;
STUCKER, JF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (22) :6022-6026
[5]   Poly(2,7-dibenzosilole): A blue light emitting polymer [J].
Chan, KL ;
McKiernan, MJ ;
Towns, CR ;
Holmes, AB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (21) :7662-7663
[6]   THE BENZANNELATION APPROACH TO NOVEL GALLIUM AND INDIUM HETEROCYCLES [J].
DECKEN, A ;
GABBAI, FP ;
COWLEY, AH .
INORGANIC CHEMISTRY, 1995, 34 (15) :3853-3854
[7]   Enantiomeric resolution and determination of the absolute configuration of dibenzophosphole 5-oxides [J].
Durán, E ;
Gordo, E ;
Granell, J ;
Font-Bardía, M ;
Solans, X ;
Velasco, D ;
López-Calahorra, F .
TETRAHEDRON-ASYMMETRY, 2001, 12 (14) :1987-1997
[8]   SYNTHESIS, CRYSTAL-STRUCTURE, DYNAMIC BEHAVIOR AND REACTIVITY OF DINAPHTHO[2,1-B/1',2'-D]PHOSPHOLES AND RELATED ATROPISOMERIC PHOSPHACYCLIC DERIVATIVES [J].
GLADIALI, S ;
DORE, A ;
FABBRI, D ;
DELUCCHI, O ;
VALLE, G .
JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (21) :6363-6371
[9]   Blue light emitting polymers [J].
Kim, DY ;
Cho, HN ;
Kim, CY .
PROGRESS IN POLYMER SCIENCE, 2000, 25 (08) :1089-1139
[10]   Structure and chemistry of 1-silafluorenyl dianion, its derivatives, and an organosilicon diradical dianion [J].
Liu, YX ;
Stringfellow, TC ;
Ballweg, D ;
Guzei, IA ;
West, R .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (01) :49-57