High-temperature oxidation behaviour of a single-phase (Mo,Ti)5Si3 (Mo-Si-Ti) alloy

被引:32
作者
Burk, Steffen [1 ]
Gorr, Bronislava [1 ]
Christ, Hans-Juergen [1 ]
Schliephake, Daniel [2 ]
Heilmaier, Martin [2 ]
Hochmuth, Christian [3 ]
Glatzel, Uwe [3 ]
机构
[1] Univ Siegen, Lehrstuhl Mat Kunde & Werkstoffprufung, D-57068 Siegen, Germany
[2] Tech Univ Darmstadt, D-64287 Darmstadt, Germany
[3] Univ Bayreuth, Lehrstuhl Metall Werkstoffe, D-95440 Bayreuth, Germany
关键词
Intermetallic phases; Silicides; High temperature oxidation; Mo-Si-B alloys; MOLYBDENUM SILICIDES; INTERMETALLICS; SYSTEM; TI5SI3;
D O I
10.1016/j.scriptamat.2011.10.042
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The alloy composition Mo-37Si-40Ti (at.%) was synthesized by arc melting in order to obtain nearly single-phase (Mo,Ti)(5)Si-3. At 750-1300 degrees C, the intermetallic compound was found to be superior to both single-phase Mo5Si3 and single-phase Ti5Si3 with regard to oxidation resistance. Upon oxidation, formation of a protective SiO2-TiO2 duplex scale was observed, which dramatically reduces outward diffusion of Ti. The results indicate that Ti alloying is a promising concept to further improve oxidation resistance of Mo-based alloys such as Mo-Si-B. (C) 2011 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:223 / 226
页数:4
相关论文
共 14 条
[1]   STURCTURE AND CHEMISTRY OF OXIDE FILMS THERMALLY GROWN ON MOLYBDENUM SILICIDES [J].
BARTLETT, RW ;
MCCAMONT, JW ;
GAGE, PR .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1965, 48 (11) :551-+
[2]   HIGH-TEMPERATURE OXIDATION .2. MOLYBDENUM SILICIDES [J].
BERKOWIT.JB .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1965, 112 (06) :583-&
[3]   Characterization of an industrially processed Mo-based silicide alloy [J].
Jéhanno, P ;
Heilmaier, M ;
Kestler, H .
INTERMETALLICS, 2004, 12 (7-9) :1005-1009
[4]  
Kubaschweski O., 1967, OXIDATION METALS ALL
[5]   Oxidation of the intermetallics MoSi2 and TiSi2 - A comparison [J].
Melsheimer, S ;
Fietzek, M ;
Kolarik, V ;
Rahmel, A ;
Schutze, M .
OXIDATION OF METALS, 1997, 47 (1-2) :139-203
[6]   Oxidation behavior of αMo-Mo3Si-Mo5SiB2 (T2) three phase system [J].
Mendiratta, MG ;
Parthasarathy, TA ;
Dimiduk, DM .
INTERMETALLICS, 2002, 10 (03) :225-232
[7]   Boron-doped molybdenum silicides [J].
Meyer, M ;
Kramer, M ;
Akinc, M .
ADVANCED MATERIALS, 1996, 8 (01) :85-&
[8]   Elevated-temperature oxidation behavior of titanium silicide and titanium silicide based alloy and composite [J].
Mitra, R ;
Rao, VVR .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 1998, 29 (06) :1665-1675
[9]   Phase stability and structural defects in high-temperature Mo-Si-B alloys [J].
Sakidja, R. ;
Perepezko, J. H. ;
Kim, S. ;
Sekido, N. .
ACTA MATERIALIA, 2008, 56 (18) :5223-5244
[10]   High temperature oxidation behavior of Ti5Si3-based intermetallics [J].
Tang, Zhihong ;
Williams, Jason J. ;
Thom, Andrew J. ;
Akinc, Mufit .
INTERMETALLICS, 2008, 16 (09) :1118-1124