Pillared-layer MOF Based on Template-directed Method: Synthesis, Structure and Proton Conduction Properties

被引：0
|
作者：
Wang Fu-Xiang [1 ]
Ren Guo-Jian [1 ]
Tian Rui-Jing [1 ]
Feng Li-Juan [1 ]
Yang Yong-Hang [1 ]
Deng Yong-Yan [2 ]
Pan Qin-He [1 ]
机构：
[1] Hainan Univ, Sch Sci, Key Lab Adv Mat Trop Isl Resources, Minist Educ, Haikou 570228, Hainan, Peoples R China
[2] Changchun Sci Tech Univ, Sch Informat Engn, Changchun 130600, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2020年 / 39卷 / 07期
基金：
中国国家自然科学基金;
关键词：
template; synthesis; metal-organic framework; pillared-layer; proton conduction; METAL-ORGANIC FRAMEWORK; CRYSTAL-STRUCTURES; ADSORPTION; SELECTIVITY; DESIGN;
D O I：
10.14102/j.cnki.0254-5861.2011-2609
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
By using Co(NH3)(6)(3+) as the template, a new complex HNU-38 was synthesized under hydrothermal reaction through the adoption of H3BTC and Cl- as the ligands (H3BTC = 1,3,5-benzenetricarboxylic acid). FIND-38 crystallized in the monoclinic system, P2(1)/1c space group with a = 9.9696(3), b = 17.0580(6), c = 16.5263(6) angstrom, beta = 100.400(2)degrees, Z = 4, V = 2764.31(16) angstrom(3), M-r = 883.63, D-c = 2.123 g/cm(3), F(000) = 1736, S = 0.920, R = 0.0358 and wR = 0.0838 (I > 2 sigma(I)). In HNU-38, the Cd2+ and BTC3- were linked together to form layers with CF serving as the pillar. It should be noted that (H2O)(n) chains were found in the channels and play a co-templating role along with the Co(NH3)(6)(3+) cations in HNU-38, and the proton conduction properties were investigated.
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收藏
页码：1337 / 1342
页数：6
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