One-Pot Conversion of Glucose into 5-Hydroxymethylfurfural using MOFs and Bronsted-Acid Tandem Catalysts

被引：30
作者：
Lara-Serrano, Marta [1 ,2 ]
Morales-delaRosa, Silvia [1 ]
Campos-Martin, Jose M. [1 ]
Abdelkader-Fernandez, Victor K. [3 ]
Cunha-Silva, Luis [3 ]
Balula, Salete S. [3 ]
机构：
[1] CSIC, Grp Energia & Quim Sostenible EQS, Inst Catilisis & Petroleoquim, C Marie Curie 2, Madrid 28049, Spain
[2] Univ Autonoma Madrid, PhD Program Appl Chem, Doctoral Sch, Madrid 28049, Spain
[3] Univ Porto, REQUIMTE LAQV, Dept Quim & Bioquim, Fac Ciencias, Rua Campo Alegre, P-4169007 Porto, Portugal
来源：
ADVANCED SUSTAINABLE SYSTEMS | 2022年 / 6卷 / 05期
关键词：
glucose conversion; HMF; MOFs; tandem catalysts; METAL-ORGANIC FRAMEWORKS; FRUCTOSE ISOMERIZATION; LEWIS; ZEOLITES; DEHYDRATION; MECHANISM; CHROMIUM; INSIGHTS; FACILE; SITES;
D O I：
10.1002/adsu.202100444
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The direct conversion reaction of glucose to 5-hydroxymethylfurfural (HMF) is studied using metal organic framework (MOF) as Lewis-acid catalysts and a polyoxometalate (POM), silicotungstic acid, as a Brensted-type acid with a mixture of 1% glucose solution in gamma-valerolactone (GVL)-10% H2O at 140 degrees C. The study is carried out with two routes: one using MOF and POM tandem catalysts added independently and the other through the synthesis of a composite material denoted POM (R) MOF. The activity tests show that the profiles of the conversion and yield of HMF achieved in both routes are similar, with the reactions with MIL 53 (Al) and MIL-101(Cr) catalysts producing the highest yield of HMF (40% after 8 h of reaction). Stability tests are performed on the POM@MOF catalysts based on MIL-53(Al) and MIL-101 (Cr). MIL-53(Al) and Hsiw@ MIL-101(Cr) can be reused, showing a progressive loss in HMF yield due to the leaching of POM.
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页数：10
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