Extraction of nanostructured starch from purified granules of waxy and non-waxy barley cultivars

被引:10
作者
Del Buono, Daniele [1 ]
Luzi, Francesca [2 ]
Benincasa, Paolo [1 ]
Kenny, Jose Maria [2 ]
Torre, Luigi [2 ]
Puglia, Debora [2 ]
机构
[1] Univ Perugia, Dept Agr Food & Environm Sci, Borgo XX Giugno 74, I-06121 Perugia, Italy
[2] Univ Perugia, Civil & Environm Engn Dept, Str Pentima 4, I-05100 Terni, Italy
关键词
Barley flours; Amylose/amylopectin ratio; Starch nanoparticles; THERMAL-PROPERTIES; PHYSICOCHEMICAL PROPERTIES; MOLECULAR-STRUCTURE; AMYLOSE CONTENT; CORN STARCHES; MAIZE; FUNCTIONALITY; PROTEIN; WHEAT; RICE;
D O I
10.1016/j.indcrop.2019.01.015
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Waxy and non-waxy barley flours were selected as native material for the extraction, by acidic hydrolysis, of starch nanoparticles (NPs), with the main aim of evaluating how their different amylose/amylopectin ratio affected NPs structural characteristics. To this scope, two approaches based, respectively, on the use of NaCl/toluene (called organic treatment) and of sodium hydroxide solutions (called alkali treatment) were adopted in order to purify the waxy flours to give starch granules. Morphological investigations of waxy flour after alkali and organic treatments, before and after acetone washing, showed that the isolation methods of the starch did not affect the general morphologic characteristics of starch granules. The method found to provide the best outcomes in terms of thermal and morphological properties was also applied to purify the non-waxy barley. The results confirmed that waxy starch characterized by granules of smaller dimensions (WS) gave amorphous nanoparticles (WNP) with reduced mean diameter and thermal stability with respect to NPs obtained from non-waxy barley flour.
引用
收藏
页码:520 / 527
页数:8
相关论文
共 55 条
[1]   Fractionation and characterization of teff proteins [J].
Adebowale, Abdul-Rasaq A. ;
Emmambux, M. Naushad ;
Beukes, Mervyn ;
Taylor, John R. N. .
JOURNAL OF CEREAL SCIENCE, 2011, 54 (03) :380-386
[2]   Optimization of the preparation of aqueous suspensions of waxy maize starch nanocrystals using a response surface methodology [J].
Angellier, H ;
Choisnard, L ;
Molina-Boisseau, S ;
Ozil, P ;
Dufresne, A .
BIOMACROMOLECULES, 2004, 5 (04) :1545-1551
[3]   Characterization and modeling of the A- and B-granule starches of wheat, triticale, and barley [J].
Ao, Zihua ;
Jane, Jay-lin .
CARBOHYDRATE POLYMERS, 2007, 67 (01) :46-55
[4]   Barley Grain Constituents, Starch Composition, and Structure Affect Starch in Vitro Enzymatic Hydrolysis [J].
Asare, Eric K. ;
Jaiswal, Sarita ;
Maley, Jason ;
Baga, Monica ;
Sammynaiken, Ramaswami ;
Rossnagel, Brian G. ;
Chibbar, Ravindra N. .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2011, 59 (09) :4743-4754
[5]   How environmental stress affects starch composition and functionality in cereal endosperm [J].
Beckles, Diane M. ;
Thitisaksakul, Maysaya .
STARCH-STARKE, 2014, 66 (1-2) :58-71
[6]   Understanding Starch Structure: Recent Progress [J].
Bertoft, Eric .
AGRONOMY-BASEL, 2017, 7 (03)
[7]   Combining mutations at genes encoding key enzymes involved in starch synthesis affects the amylose content, carbohydrate allocation and hardness in the wheat grain [J].
Botticella, Ermelinda ;
Sestili, Francesco ;
Sparla, Francesca ;
Moscatello, Stefano ;
Marri, Lucia ;
Cuesta-Seijo, Jose A. ;
Falini, Giuseppe ;
Battistelli, Alberto ;
Trost, Paolo ;
Lafiandra, Domenico .
PLANT BIOTECHNOLOGY JOURNAL, 2018, 16 (10) :1723-1734
[8]   Starch in rubbery and glassy states by FTIR spectroscopy [J].
Capron, Isabelle ;
Robert, Paul ;
Colonna, Paul ;
Brogly, Maurice ;
Planchot, Veronique .
CARBOHYDRATE POLYMERS, 2007, 68 (02) :249-259
[9]   Variation in crystalline type with amylose content in maize starch granules: an X-ray powder diffraction study [J].
Cheetham, NWH ;
Tao, LP .
CARBOHYDRATE POLYMERS, 1998, 36 (04) :277-284
[10]   IMPROVED COLORIMETRIC DETERMINATION OF AMYLOSE IN STARCHES OR FLOURS [J].
CHRASTIL, J .
CARBOHYDRATE RESEARCH, 1987, 159 (01) :154-158