Synthesis and Applications of Functionalized Magnetic Nanomaterials in Enantioseparation

被引:25
作者
Deng, Xiaojuan [1 ,2 ]
Li, Wenbin [3 ]
Ding, Guosheng [2 ]
Xue, Tao [2 ]
Chen, Xiaoping [2 ]
机构
[1] Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China
[2] Tianjin Univ, Anal Ctr, Tianjin, Peoples R China
[3] Dikma Technol Inc, Tianjin, Peoples R China
基金
中国国家自然科学基金;
关键词
Magnetic nanomaterials; enantioseparation; chiral selector; beta-cyclodextrin; polymer; protein; amino acids; cellulose; CHIRAL STATIONARY PHASES; METAL-ORGANIC FRAMEWORKS; CE RECENT DEVELOPMENTS; AROMATIC-AMINO-ACIDS; CAPILLARY-ELECTROPHORESIS; LIQUID-CHROMATOGRAPHY; ENANTIOSELECTIVE CRYSTALLIZATION; ENANTIOMERIC SEPARATION; BIOMEDICAL APPLICATIONS; SILICA NANOPARTICLES;
D O I
10.1080/15422119.2017.1419257
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Efficient enantioselective separation is a challenging task due to the identical physical and chemical properties of enantiomers. Functionalized magnetic nanomaterials modified with chiral ligands on their surface possess both magnetic property and chiral recognition ability, and have demonstrated great potential in chiral discrimination. This review summarizes the applications of magnetic nanomaterials modified with various chiral selectors (e.g., beta-cyclodextrins, polymers, proteins, amino acids and cellulose) in enantioselective separation. After proper preparation and modification, these functionalized magnetic nanomaterials are effective for enantioseparation. Therefore, enantioseparations based on functionalized magnetic nanomaterials are convenient, economical and effective.
引用
收藏
页码:14 / 29
页数:16
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