Preparation, characterization, and photocatalytic properties of silver carbonate

被引:145
作者
Xu, Chengwei
Liu, Yuanyuan [1 ,2 ]
Huang, Baibiao [1 ,2 ]
Li, Hui [3 ]
Qin, Xiaoyan [1 ,2 ]
Zhang, Xiaoyang [1 ,2 ]
Dai, Ying [4 ]
机构
[1] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
[2] Shandong Univ, Hosp 2, Dept Lab Med, Jinan 250033, Peoples R China
[3] Shandong Expt Senior High Sch, Dept Chem, Jinan 250001, Peoples R China
[4] Shandong Univ, Sch Phys, Jinan 250100, Peoples R China
基金
中国国家自然科学基金;
关键词
Silver carbonate; Photocatalysis; Antibacterial activity; VISIBLE-LIGHT IRRADIATION; AG-AT-AGCL; ESCHERICHIA-COLI; HIGHLY EFFICIENT; HYDROGEN-PRODUCTION; SEMICONDUCTOR; WATER; DEGRADATION; ELECTRODE;
D O I
10.1016/j.apsusc.2011.05.060
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Silver carbonate (Ag2CO3) short rods were prepared using a precipitation method. It was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), diffuse reflective spectra (DRS) and photocatalytic degradation of organic pollutants and destruction of E. coli measurements. The results of DRS suggested that the optical transition of Ag2CO3 was indirectly allowed, and its band gap was determined to be 2.08 eV. The prepared Ag2CO3 displayed a high activity towards degradation of phenol and MB under visible light. The total organic carbon (TOC) value decreased during the photocatalytic process, which suggests that phenol was truly photodegraded. The stability of Ag2CO3 was greatly improved when Na2CO3 was added into the photocatalytic system. In addition, Ag2CO3 displayed enhanced photocatalytic activities for the destruction of E. coli due to its photogenerated electron-hole pairs. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:8732 / 8736
页数:5
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