Co3O4 Catalysts on CeO2-ZrO2 Supports and Co3O4-CeO2 Catalysts on Al2O3/SiO2 Supports for the Oxidation of Propylene

被引:3
作者
Tien The Nguyen [1 ]
Phuong ThiMai Pham [1 ]
Thang Minh Le [2 ]
Isabel Van Driessche [3 ]
机构
[1] Hanoi Univ Sci & Technol, Adv Inst Sci & Technol, Lab Environm Friendly Mat & Technol, Hanoi 10000, Vietnam
[2] Hanoi Univ Sci & Technol, Sch Chem Engn, Dept Organ & Petrochem, Hanoi 10000, Vietnam
[3] Univ Ghent, SCRiPTS, Dept Inorgan & Phys Chem, B-9000 Ghent, Belgium
关键词
COBALT OXIDE CATALYSTS; MIXED-OXIDE; COMBUSTION; CO; SURFACE; CERIA; ALUMINA; METHANE;
D O I
10.1155/2015/912905
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Different compositions of Co3O4 catalysts on CeO2-ZrO2 solid solution (Ce0.9Zr0.1O2 and Ce0.8Zr0.2O2) have been studied for the oxidation of propylene. The optional amount of Co3O4 active phase on CeO2-ZrO2 support of 30 wt% was found. The mixed Co3O4-CeO2-ZrO2 with the same composition of the optimal supported ones showed approximately the same activity, which was not higher than the activity of the mixed Co3O4-CeO2 catalyst. Catalytic activities of mixed Co3O4-CeO2 with different loading contents supported on high surface area supports (Al2O3, SiO2) were then measured. The optimal composition of active phase was still 30 wt% but the minimum temperature of the highest activity increased to above 300 degrees C due to the inert nature influence of the support.
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页数:8
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