Amorphous transitional metal borides as substitutes for Pt cocatalysts for photocatalytic water splitting

Cocatalysts for H-2 production are often made from noble metals, which are expensive and rare. Cocatalysts made from cheap and abundant elements are therefore highly desirable for economically viable H-2 production. Here, we demonstrate that amorphous transitional metal borides (TMBs) made from abundant materials and costing less than 0.1% of the price of Pt cocatalysts are effective substitutes for Pt-based cocatalysts and result in superior H-2 production via water-splitting under visible light irradiation. Under visible-light driven photocatalytic water-splitting, using TMBs as cocatalysts for nanostructured NiCoB/CdS composites achieved an extraordinary H-2 production of 144.8 mmol h(-1) g(-1), up to 36 times greater than that observed when using CdS alone. The apparent quantum efficiency was measured as 97.42% at 500 nm, which is the highest value reported for CdS photocatalysts. The hydrogen atom adsorption energy (Delta E(H)) and hydrogen molecule adsorption energy (Delta E(H-2)) of NiB, NiCoB and Pt have been calculated for the first time. Compared with Pt cocatalyst, amorphous TMBs cocatalysts more readily adsorb hydrogen protons and desorb molecular hydrogen during the photocatalytic process. Superior performance of TMBs as cocatalyst, much better than Pt, can be attributed to its powerful trapping electrons ability and highly adsorption of protons. These findings provide a straightforward and effective route to produce cheap and efficient cocatalysts for large-scale water splitting. (C) 2016 The Authors. Published by Elsevier Ltd.