Amphiphilic Folded Dendrimer Discs and Their Thermosensitive Self-Assembly in Water

被引:28
|
作者
El Malah, Tamer [2 ]
Rolf, Simone [1 ]
Weidner, Steffen M. [1 ]
Thuenemann, Andreas F. [1 ]
Hecht, Stefan [2 ]
机构
[1] BAM Fed Inst Mat Res & Testing, D-12205 Berlin, Germany
[2] Humboldt Univ, Dept Chem, D-12489 Berlin, Germany
关键词
click chemistry; Cotton effect; dendrimers; hierarchical self-assembly; thermochemistry; DENDRONS; POLYMERS; ARCHITECTURES; TEMPERATURE; COMPLEXES; FOLDAMERS; GROWTH;
D O I
10.1002/chem.201200414
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Folded dendrimers with peripheral ether side chains show a thermally induced hierarchical aggregation process, in which the transition temperature and the dimensions of the aggregates can readily be tuned via the generation number (see figure). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:5837 / 5842
页数:6
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