Coordination chemistry of iron triad metals with organic N-donor ligands and boron cluster anions [B10H10]2-, [B12H12]2-, and [B10Cl10]2-: Complexation and accompanying processes

被引：44

作者：

Avdeeva, V. V. ^{[1
]}

Malinina, E. A. ^{[1
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2017年 / 62卷 / 13期

基金：

俄罗斯科学基金会;

关键词：

CLOSO-DECABORATE ANION; NICKEL(II) COMPLEXES; CRYSTAL-STRUCTURE; BNHN2-N=6; H N; COBALT(II); 1,10-PHENANTHROLINE; BIPY; DMSO; REACTIVITY;

D O I：

10.1134/S0036023617130022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis and structures of coordination compounds of the iron triad metals with N-donor ligands (Bipy, Phen, and BPA) and boron cluster anions [B10H10](2-), [B12H12](2-), and [B10Cl10](2-) are described. The processes of complexation and accompanying redox reactions involving the metal atoms and boron clusters and substitution of exo-polyhedral hydrogen atoms in the decahydro-closo-decaborate anion are considered. The conditions under which the accompanying reactions become the main processes and predominate over complexation are determined.

引用

页码：1673 / 1702

页数：30

共 33 条

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