Electronic and Vibrational Dynamics of Hollow Au Nanocages Embedded in Cu2O Shells

We have synthesized hollow Au nanocages embedded within thick porous shells of cuprous oxide (Cu2O). The shell causes a significant redshift of the localized surface plasmon resonance of Au into the near-IR. Electron-phonon coupling in the Au nanocage is 3-6 times faster in the core-shell structure due to the higher thermal conductivity of Cu2O compared to water. Coherent phonon oscillations within the Au lattice are characterized by a breathing mode of the entire structure for both bare and core-shell nanocages, an assignment made through the use of structural mechanics simulations. The experimental frequencies are obtained through simulations by selectively applying a force to the shell of the core-shell structure. We interpret this as rapid thermal expansion of the gold leading to a mechanical force that acts on the shell.