Sophisticated Crystal Transformation of a Coordination Polymer into Mesoporous Monocrystalline Ti-Fe-Based Oxide with Room-Temperature Ferromagnetic Behavior

被引：20

作者：

Hu, Ming ^{[1
]}

Belik, Alexei A. ^{[1
]}

Sukegawa, Hiroaki ^{[2
]}

Nemoto, Yoshihiro ^{[1
]}

Imura, Masataka ^{[1
]}

Yamauchi, Yusuke ^{[1
,3
]}

机构：

[1] NIMS, World Premier Int WPI Res Ctr Mat Nanoarchitecton, Tsukuba, Ibaraki 3050044, Japan

[2] NIMS, Magnet Mat Unit, Spintron Grp, Tsukuba, Ibaraki 3050044, Japan

[3] PRESTO Japan Sci & Technol Agcy JST, Kawaguchi, Saitama 3320012, Japan

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2011年 / 6卷 / 12期

关键词：

crystal growth; iron; mesoporous materials; polymers; titanium; METAL-ORGANIC FRAMEWORKS; PRUSSIAN BLUE NANOPARTICLES; MOLECULAR-SIEVES; FACILE SYNTHESIS; SILICA MCM-41; PORE-SIZE; TEMPLATE; CONVERSION; WALLS; STORAGE;

D O I：

10.1002/asia.201100509

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Have you been framed? Mesoporous monocrystalline K0.8Ti 4.3Fe3.7O16 cubes have been prepared by a sophisticated crystal transformation from a single-crystalline titanium-containing Prussian Blue analogue. This is a new strategy for the design of fully crystallized frameworks in mesoporous materials (see graphic). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3195 / 3199

页数：5

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