Isothermal Vapor-Liquid Equilibria for Binary Mixtures of Methyl Nonafluorobutyl Ether plus Acetone, Cyclopentyl Methyl Ether, Ethyl Acetate, n-Heptane, Methanol, and Toluene

被引：15

作者：

Rehak, Karel ^{[1
]}

Klajmon, Martin ^{[1
]}

Strejc, Martin ^{[1
]}

Moravek, Pavel ^{[1
]}

机构：

[1] Univ Chem & Technol, Dept Phys Chem, Prague 16628 6, Czech Republic

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2017年 / 62卷 / 11期

关键词：

EQUATION-OF-STATE; PERTURBED-CHAIN SAFT; EXCESS MOLAR ENTHALPIES; PHASE-EQUILIBRIA; THERMODYNAMIC PROPERTIES; HYDROFLUOROETHERS; PRESSURE; VOLUMES; SYSTEMS; POLYDISPERSE;

D O I：

10.1021/acs.jced.7b00599

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Measurements of vapor-liquid equilibrium data in binary systems methyl nonafluorobutyl ether + solvent (acetone, cyclopentyl methyl ether, ethyl acetate, n-heptane, methanol, and toluene) were carried out at constant temperature (328.15 or 318.15 K) by means of a vapor-liquid equilibrium circulation still. In the most cases, the acquired data satisfied thermodynamic consistency tests. The obtained vapor-liquid equilibrium data were (successfully) correlated by two principally different thermodynamic models: the nonrandom two-liquid equation for the excess Gibbs energy, and the perturbed-chain statistical associating fluid theory equation of state. The latter model was tested also for its predictive capabilities and was found not to be suitable for reliable predictions in the studied binary systems, although it may correctly predict the azeotropic behavior of some systems.

引用

页码：3878 / 3888

页数：11

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