Polyvinylpolypyrrolidoniume tribromide as new and metal-free catalyst for the formylation and trimethylsilylation of hydroxyl group

被引：22

作者：

Ghorbani-Choghamarani, Arash ^{[1
]}

Goudarziafshar, Hamid ^{[1
]}

Zamani, Parisa ^{[1
]}

机构：

[1] Ilam Univ, Fac Sci, Dept Chem, Ilam, Iran

来源：

CHINESE CHEMICAL LETTERS | 2011年 / 22卷 / 10期

关键词：

Polyvinylpolypyrrolidone; Polyvinylpolypyrrolidoniume tribromide; Formylation; Silylation; Ethyl format; 1,1,1,3,3,3-Hexamethyldisilazane (HMDS); SILICA SULFURIC-ACID; IN-SITU GENERATION; HYDROGEN SULFATE; HETEROGENEOUS CONDITIONS; COMBINATION REAGENT; AROMATIC-AMINES; OXIDIZING-AGENT; MILD CONDITIONS; SODIUM-NITRITE; ETHYL FORMATE;

D O I：

10.1016/j.cclet.2011.05.020

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Trimethylsilylation of alcohols was achieved using 1,1,1,3,3,3-hexamethyldisilazane (HMDS) as silylating agent, in the presence of polyvinylpolypyrrolidoniume tribromide in acetonitrile at room temperature. Also a variety of alcohols were converted into alkyl formates by ethyl formate and a catalytic amount of polyvinylpolypyrrolidoniume tribromide under solvent free conditions at room temperature. (C) 2011 Arash Ghorbani-Choghamarani. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

引用

页码：1207 / 1210

页数：4

共 21 条

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