Structural Diversity of Cationic Copper(II) Complexes with Neutral Nitrogen-Containing Organic Ligands in Compounds with Boron Cluster Anions and Their Derivatives (Review)

被引：31

作者：

Avdeeva, V. V. ^{[1
]}

Malinina, E. A. ^{[1
]}

Zhizhin, K. Yu. ^{[1
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2020年 / 65卷 / 04期

关键词：

decahydro-closo-decaborate anion; dodecahydro-closo-dodecaborate anion; decachloro-closo-decaborate anion; octadecahydro-eicosaborate anion; complexes; copper; CLOSO-DECABORATE ANION; N-DONOR LIGANDS; CRYSTAL-STRUCTURE; COORDINATION CHEMISTRY; DODECABORATE ANION; SUBSTITUTION; CARBORANE; REDOX; SALTS; BIPY;

D O I：

10.1134/S0036023620040026

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Data on the known-to-date copper(II) complexes with neutral nitrogen-containing ligands (2,2'-bipyridyl, 1,10-phenanthroline, 2,2'-bipyridylamine, aminoguanidine, ammonia, pyridine derivatives, etc.) with boron cluster anions, including those containing bridging OH- and groups, are generalized. Mono-, di-, tri-, tetranuclear, and polymer copper(II) complexes are considered; the geometry of copper(II) coordination polyhedra, structural features of complex compounds, and methods for their preparation are discussed. The boron cluster anions [B10H10]2-, [B12H12]2-, [B10Cl10]2-, [ B20H18]2- and their derivatives (substituted derivatives, carboranes, and metallacarboranes) have been chosen as counterions.

引用

页码：514 / 534

页数：21

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