Mild and efficient oxidation of phosphorus(III) compounds with Selectfluor

被引：11

作者：

Chen, Qian ^{[1
]}

Zeng, Jiekun ^{[1
]}

Yan, Xinxing ^{[1
]}

Huang, Yulin ^{[1
]}

Du, Zhiyun ^{[1
]}

Zhang, Kun ^{[1
]}

Wen, Chunxiao ^{[1
]}

机构：

[1] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Guangdong, Peoples R China

来源：

TETRAHEDRON LETTERS | 2016年 / 57卷 / 30期

基金：

中国国家自然科学基金;

关键词：

Phosphines; Phosphine oxides; Oxidation; Selectfluor; SECONDARY PHOSPHINE OXIDES; ENANTIOSELECTIVE HYDROGENATION; ASYMMETRIC HYDROGENATION; ELECTRON-TRANSFER; RADICAL CATIONS; LIGANDS; REDUCTION; TRIPHENYLPHOSPHINE; OXYGEN; DERIVATIVES;

D O I：

10.1016/j.tetlet.2016.06.078

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel and efficient oxidation of phosphorus(III) compounds with Selectfluor is described. The reactions smoothly led to the formation of tertiary phosphine oxides, phosphinates, and phosphonates in up to 99% yield under mild conditions in minutes. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：3379 / 3381

页数：3

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