Mild and efficient oxidation of phosphorus(III) compounds with Selectfluor

被引：11
作者：
Chen, Qian [1 ]
Zeng, Jiekun [1 ]
Yan, Xinxing [1 ]
Huang, Yulin [1 ]
Du, Zhiyun [1 ]
Zhang, Kun [1 ]
Wen, Chunxiao [1 ]
机构：
[1] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Guangdong, Peoples R China
来源：
TETRAHEDRON LETTERS | 2016年 / 57卷 / 30期
基金：
中国国家自然科学基金;
关键词：
Phosphines; Phosphine oxides; Oxidation; Selectfluor; SECONDARY PHOSPHINE OXIDES; ENANTIOSELECTIVE HYDROGENATION; ASYMMETRIC HYDROGENATION; ELECTRON-TRANSFER; RADICAL CATIONS; LIGANDS; REDUCTION; TRIPHENYLPHOSPHINE; OXYGEN; DERIVATIVES;
D O I：
10.1016/j.tetlet.2016.06.078
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel and efficient oxidation of phosphorus(III) compounds with Selectfluor is described. The reactions smoothly led to the formation of tertiary phosphine oxides, phosphinates, and phosphonates in up to 99% yield under mild conditions in minutes. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3379 / 3381
页数：3
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