Activation of "Inert" Alkenyl/Aryl C-O Bond and Its Application in Cross-Coupling Reactions

被引：422

作者：

Li, Bi-Jie ^{[1
,2
,3
]}

Yu, Da-Gang ^{[1
,2
,3
]}

Sun, Chang-Liang ^{[1
,2
,3
]}

Shi, Zhang-Jie ^{[1
,2
,3
,4
]}

机构：

[1] Peking Univ, BNLMS, Beijing 100871, Peoples R China

[2] Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Minist Educ, Coll Chem, Beijing 100871, Peoples R China

[3] Peking Univ, Green Chem Ctr, Beijing 100871, Peoples R China

[4] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 06期

关键词：

C-O activation; cross-coupling; enol; phenol; transition metals; PALLADIUM-CATALYZED AMINATION; NUCLEOPHILIC AROMATIC-SUBSTITUTION; DIRECTED ORTHO-METALATION; ORGANO-ALUMINUM COMPOUNDS; HETEROARYL BORONIC ACIDS; CARBON-CARBON BONDS; SUZUKI-MIYAURA; GRIGNARD-REAGENTS; ARYL TOSYLATES; ARYLBORONIC ACIDS;

D O I：

10.1002/chem.201002273

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Enol and phenol functionalities are very common in organic molecules. Utilization of these materials is very appealing in organic synthesis because they are important alternatives to organohalides in cross-coupling reactions. In this review, we summarize the transition-metal-catalyzed cross-coupling of enol- and phenol-based electrophiles, including phosphates, sulfonates, ethers, carboxylates, and phenolates.

引用

页码：1728 / 1759

页数：32

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