1,3-bis[2-(dimethylaminomethyl)-phenyl]triselenide

被引:9
作者
Kulcsar, Monika
Silvestru, Anca
Cziple, Florentina
机构
[1] Univ Babes Bolyai, Fac Chem & Chem Engn, RO-400028 Cluj Napoca, Romania
[2] Eitimie Murugu Univ, RO-320085 Resita, Romania
来源
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2007年 / 63卷 / o701-o703期
关键词
D O I
10.1107/S0108270107051591
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, C18H24N2Se3, consists of discrete molecules; owing to the presence of strong intramolecular N center dot center dot center dot Se interactions [N center dot center dot center dot Se = 2.671 (4) and 2.873 (4) angstrom], the chalcogen Se atoms of the angular Se-3 chain exhibit different coordination geometries, i.e. the terminal Se atoms are tricoordinated and exhibit a T-shaped environment of the CNSe2 core [N center dot center dot center dot Se-Se = 173.73 (9) and 172.29 (9)degrees], while the central Se atom is dicoordinated to the other two Se atoms, with an Se-Se-Se angle of 108.32 (2)degrees.
引用
收藏
页码:O701 / O703
页数:3
相关论文
共 24 条
[1]   Synthesis of 4-(phenylamino)quinazoline-2(1H)-selones and diselenides from isoselenocyanates:: Dimroth rearrangement of an intermediate [J].
Atanassov, PK ;
Linden, A ;
Heimgartner, H .
HELVETICA CHIMICA ACTA, 2004, 87 (07) :1873-1887
[2]  
BRANDENBURG K, 2006, DIAMOND REL 3 1D
[3]  
*BRUK AXS INC, 2000, SMART VERS 5 054 SAI
[4]  
*BRUK AXS INC, 2001, SHELXTL VERS 6 12
[5]   Hypervalent selenium compounds containing N → Se intramolecular interactions:: synthesis, characterization and X-ray structures of [2-(Me2NCH2)C6H4]SeS(S)PR2 (R=Ph, OiPr) [J].
Deleanu, C ;
Drake, JE ;
Hursthouse, MB ;
Kulcsar, M ;
Light, ME ;
Silvestru, A .
APPLIED ORGANOMETALLIC CHEMISTRY, 2002, 16 (12) :727-731
[6]   Hypervalent tellurium compounds containing N→Te intramolecular interactions.: Crystal and molecular structure of [2-(Me2NCH2)C6H4]2Te2, [2-(Me2NCH2)C6H4]TeS(S)PR2 (R = Me, Ph, OPri) and [2-(Me2NCH2)C6H4]Te-S-PPh2=N-PPh2=S [J].
Drake, JE ;
Hursthouse, MB ;
Kulcsar, M ;
Light, ME ;
Silvestru, A .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 623 (1-2) :153-160
[7]   Hypervalent Tellurium Compounds Containing Te-N Interactions. Mononuclear and Polynuclear Derivatives [J].
Drake, John. E. ;
Hursthouse, Michael. B. ;
Kulcsar, Monika ;
Light, Mark. E. ;
Silvestru, Anca .
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2001, 169 (01) :293-296
[8]  
Emsley, 1994, DIE ELEMENTE
[9]   STRUCTURAL ASPECTS OF STABLE DIBENZYL TRISELENIDES - THE CRYSTAL-STRUCTURES OF BIS(2,4-DICHLOROBENZYL) TRISELENIDE AND BIS(2,6-DICHLOROBENZYL) TRISELENIDE [J].
HANSEN, F ;
HENRIKSEN, L ;
LARSEN, S ;
TEUBER, L .
ACTA CHEMICA SCANDINAVICA, 1989, 43 (05) :450-457
[10]  
IUPAC, 1979, NOM ORG CHEM